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Lanthanum Hexaboride/Lanthanum Boride

Lanthanum Hexaboride/Lanthanum Boride/LaB6/LaB Powder 12008-21-8

Lanthanum Hexaboride (LaB6, also called Lanthanum Boride and LaB) is an inorganic chemical, a boride of lanthanum. As refractory ceramic material that has a melting point of 2210 °C, Lanthanum Boride is highly insoluble in water and hydrochloric acid, and converts to the oxide when heated (calcined). Stoichiometric samples are colored intense purple-violet, while boron-rich ones (above LaB6.07) are blue. Lanthanum Hexaboride (LaB6) is known for its hardness, mechanical strength, thermionic emission, and strong plasmonic properties. Recently, a new moderate-temperature synthetic technique was developed to directly synthesize LaB6 nanoparticles.


Lanthanum Hexaboride

Synonym Lanthanum Boride
CASNo. 12008-21-8
Chemical formula LaB6
Molar mass 203.78g/mol
Appearance intense purple violet
Density 4.72g/cm3
Melting point 2,210°C(4,010°F;2,480K)
Solubility in water insoluble

 

Particle Size of Lanthanum Hexaboride

50nm 100nm 500nm 1μm  5μm  8μm1  2μm  18μm  25μm

 

What is Lanthanum Hexaboride (LaB₆) used for?

Applications of Lanthanum Hexaboride (LaB₆)  

Lanthanum Hexaboride (LaB₆), a rare-earth boride compound, is renowned for its exceptional electron emission properties, thermal stability, and chemical resistance. Its unique combination of high melting point (~2,710°C), low work function, and durability makes it indispensable in advanced electronics, analytical instrumentation, and cutting-edge technologies. Below are its key uses:  

 

1. High-Performance Electron Emission Systems

Electron Beam Sources:  

Superior Cathode Material: Replaces traditional tungsten cathodes in high-power electron emission systems due to its lower work function** (2.4–2.8 eV) and higher current density, ensuring brighter, more stable electron beams.  

Critical Applications:  

  Electron Microscopes: Enhances resolution and longevity in scanning electron microscopes (SEMs) and transmission electron microscopes (TEMs).  

  Electron Beam Lithography: Enables ultra-precise nanofabrication for semiconductor and photonic devices.  

  Free Electron Lasers (FELs): Powers high-energy electron beams for scientific research and medical imaging.  

Microwave & Vacuum Tubes:  

  Used in magnetrons, klystrons, and traveling-wave tubes (TWTs) for radar systems, satellite communications, and defense technologies.  

 

2. Advanced Manufacturing & Materials Science  

Electron Beam Welding & Heating:  

  Provides highly focused heat sources for precision welding, additive manufacturing, and surface treatment in aerospace and automotive industries.  

Coatings & Thin Films:  

  Applied as protective coatings on turbine blades, rocket nozzles, and nuclear reactor components to resist extreme temperatures and oxidation.  

Single-Crystal LaB₆:  

  Serves as a premium cathode material in particle accelerators, synchrotrons, and ion implantation systems.  

 

3. Analytical Instrumentation  

X-Ray Diffraction (XRD) Standards:  

   Acts as a certified size/strain reference material to calibrate instrumental broadening in XRD analysis, ensuring accuracy in crystallographic studies.  

X-Ray Tubes:  

   Enhances brightness and efficiency in medical and industrial X-ray sources.  

 

4. Emerging & Niche Technologies  

Quantum Computing & Research:  

   Investigated for use in quantum emitters and spintronic devices due to its low electron scattering and high carrier mobility.  

Plasma Display Panels (PDPs):  

   Improves efficiency and lifespan in high-definition displays.  

Space Exploration:  

   Utilized in ion thrusters and spacecraft sensors for deep-space missions.  

 

5. Industrial & Environmental Applications  

High-Temperature Sensors:  

   Functions in thermocouples and thermal probes for metallurgical processes and molten metal monitoring.  

Superconducting Materials:  

   Explored in superconducting composites for energy storage and magnetic levitation systems.  

 

Key Advantages of LaB₆  

Ultra-High Thermal Stability: Maintains performance in extreme environments (up to 1,800°C in vacuum).  

Chemical Inertness: Resists corrosion from acids, alkalis, and reactive gases.  

Longevity: Outperforms tungsten cathodes by 10–20x in operational lifespan.  

 

Industry-Specific Benefits  

Aerospace & Defense: Reliable radar systems, satellite communications, and thermal protection coatings.  

Semiconductors: Enables next-generation lithography for sub-5nm chip fabrication.  

Research & Healthcare: High-resolution imaging in TEMs and advanced X-ray diagnostics.  

 

Lanthanum Hexaboride is a cornerstone of modern high-tech industries, driving innovation in nanotechnology, energy, and quantum sciences. Its unparalleled electron emission capabilities and robustness solidify its role as a critical material for both current and next-generation technologies.  

 

Note: LaB₆ nanoparticles are increasingly used in field-emission displays (FEDs) and nanoelectronics, highlighting its adaptability to evolving technological demands.

 

 

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Rare Earth Fluorides Lanthanum Hexaboride/Lanthanum Boride/LaB6/LaB Powder 12008-21-8
Lanthanum Hexaboride (LaB6, also called Lanthanum Boride and LaB) is an inorganic chemical, a boride of lanthanum. As refractory ceramic material that has a melting point of 2210 °C, Lanthanum Boride is highly insoluble in water and hydrochloric acid, and converts to the oxide when heated (calcined). Stoichiometric samples are colored intense purple-violet, while boron-rich ones (above LaB6.07) are blue. Lanthanum Hexaboride (LaB6) is known for its hardness, mechanical strength, thermionic emission, and strong plasmonic properties. Recently, a new moderate-temperature synthetic technique was developed to directly synthesize LaB6 nanoparticles.
Learn More

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